Microwave assisted covalent functionalization of C(60)@SWCNT peapods.

نویسندگان

  • Nikolaos Karousis
  • Solon P Economopoulos
  • Yoko Iizumi
  • Toshiya Okazaki
  • Zheng Liu
  • Kazu Suenaga
  • Nikos Tagmatarchis
چکیده

The covalent functionalization of the external wall of C(60)@SWCNT peapods, by in situ generated aryl diazonium salts, assisted by microwave irradiation is reported. Spectroscopic, thermal and microscopy characterization was performed. Electrochemistry revealed the three reversible reductions of encapsulated C(60), however, shifted towards positive potentials when compared with those of intact C(60).

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عنوان ژورنال:
  • Chemical communications

دوره 46 48  شماره 

صفحات  -

تاریخ انتشار 2010